Liquid crystal (LC) has long been a feature in Materials Science and Nanotechnology, have  recently been extended into the appealing domain of complex hybrid materials. The crystalline  structural effects of alkoxy chain lengths and the mesogen properties of hydrogen-bonded (nOBASA) complexes (n=5,6,7) have been investigated in recent studies. The LC-based hybrid  nanocomposite materials –obtained by the homogeneous dispersion of zinc oxide nanowires  (ZnO NWs) as a dopant into hydrogen-bonded liquid-crystalline (HBLC) compounds– seem to  be particularly promising in this article. Optimizing the geometry of surface stabilizing electrooptic, LC cell reveals the typical intermolecular hydrogen bond (H-bond) formation. Here, we  explore molecular-colloidal hybrid composite matrix formed from LCs and dilute dispersions of  orientation-ordered ZnO NWs, for eventual potential application in smart switchable display devices. In addition, we investigated the structural, dielectric and optical properties of the  nanocomposite, and electro-optical studies which were performed by exploiting the potential  during the conditions before the opening of spectrum acquisition. Our novel findings confirm  that the electric field induces a charge transfer of the LC molecules to the nanomaterial, which  acts as a trap for ionic charges. This effect may be utilized to achieve switching that is electro optically tunable. Such dynamic switching could be harnessed in smart LCD technology and pave the way towards innovative display modulation technology.